October 12, 2009

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Growing Geodesic Carbon Nanodomes

Tiny carbon islands bubble up at the center to form nanoscopic geodesic domes

Geodesic Carbon Nanodomes

Illustration: Alan Stonebraker

Carbon dome structure on an iridium substrate, indicating the tightly bound atoms at the edge of the island (C), the weakly bound atoms at the center (B) and intermediate atoms (A).
Article in Physics
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COLLEGE PARK, MD – Researchers analyzing the assembly of graphene (sheets of carbon only one atom thick) on a surface of iridium have found that the sheets grow by first forming tiny carbon domes. The discovery offers new insight into the growth of graphene layers and points the way to possible methods for assembling components of graphene-based computer circuits.  

Paolo Lacovig, Monica Pozzo, Dario Alfè, Paolo Vilmercati, Alessandro Baraldi, and Silvano Lizzit at institutions in Italy, the UK and USA report their discovery in a paper appearing October 12 in the journal Physical Review Letters. The researchers' spectroscopic study suggests that graphene grows in the form of tiny islands built of concentric rings of carbon atoms. 

The islands are strongly bonded to the iridium surface at their perimeters, but are not bonded to the iridium at their centers, which causes them to bulge upward in the middle to form minuscule geodesic domes. By adjusting the conditions as the carbon is deposited on the iridium, the researchers could vary the size of the carbon domes from a few nanometers to hundreds of nanometers across. 

Investigating the formation of graphene nanodomes helps physicists to understand and control the production of graphene sheets. In combination with methods for adjusting the conductivity of graphene and related materials, physicists hope to replace electronics made of silicon and metal with tiny, efficient carbon-based chips. 

Jorge Sofo and Renee Diehl (Penn State University) highlight the graphene nanodome research in a Viewpoint in the October 12 issue Physics. 

Also in Physics

• Viewpoint by Robert Klie (University of Illinois at Chicago) describes an approach for reducing aberrations in electron microscopy, setting a new standard for low-energy imaging.
   
  
• Synopsis by Abishek Agarwal (American Physical Society) offers a model that suggests that quark-gluon plasmas produced in particle colliders could emit the briefest light bursts yet, potentially offering illumination for ultra-fast images of high speed events in atomic and molecular experiments.

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